The "building envelope" is made by the elements (walls, windows, slabs, roof etc.) that separates the heated/cooled volume of the building from the outside and from other parts of the buildings (garages, stairwell etc.) that do not require heating/cooling. The envelope is the insulated "box" that keeps your building warm in winter and cool in summer.
The "opaque envelope" means all elements that do not allow sun radiation to reach the inside of the envelope: this means: all walls, roofs and slabs that are not transparent. Normal walls, slabs and roofs belong to the opaque envelope.
Back to the glazing, yes the TST is the parameter we need. Unfortunately, ED only allows you to set the TOTAL solar transmission, without making any difference between light radiation and infra-red radiation.
Anyway, keep in mind that the glazing standard for passive houses follows these two rules:
Ug (U-value of the glass alore, without the frame) <= 0,7 W/m2K (I don't know if you can set this value in ED)
Uw (U-value of the whole window, including the frame. In this case, not including the thermal bridge caused by the installation of the window) <=0,8 W/m2K (this is the U value you need to enter in ED). You entered Uw=0,60 W/m2K: did you calculate that? It seems very low to be realistic.
Ug - 1,6 * g <= 0
where "g" is your TST value
If you keep your Uw=0,60, then you need to have a 3-pan low-e glazing with Xenon gas (I hope you're not paying for this project personally) with 6-16-4-16-6 glazing and Ug=0,40 W/m2K. A typical g value for such glazing is about 0,43-0,48 (also see "Technologie und Wirtschaft des Passivhauses by Stefan Echterholter, published by Diplom.de, in German).
0,40 - 1,6*g <=0
In this case:
0,40 - 1,6*0,43 <= 0
-0,77<0 : the glazing is suitable for a passive house.
To summarize:
U-value = 0,60 (to include the Uf value of the window frame)
TST/ g value = 0,43
This will let less energy into the building, allowing for less passive heating in winter (which you do not need) and protecting your building better from overheating in summer.
Further development for your project would be to study which part of the glazing needs to have this kind of Formula-1 glass, and where you can use cheaper options.