The same sort of colour adjustments you would make in photo editing software, are available in the cinerender material settings. Changing the hue, saturation etc by adding a layer.
However the more complex preset materials use a lot of layers (again much like image editing software) to create the colour. Often there are random generated 'noise' layers to reduce the repition you would get from just a texture.
A quick way to determine which settings (besides the obvious 'color') are affecting the colour settings, you can untick the settings one by one to see how they are affecting the material.
It is not so much complex as it is time consuming in my experience.
The help file is quite extensive as is the help center and I find the youtube tutorials on materials help as well.
Erwin Edel, Project Lead, Leloup Architecten
www.leloup.nlArchiCAD 9-26NED FULL
Windows 10 Pro
Adobe Design Premium CS5